Iris Publishers - Modern Concepts in Material Science
Pairs of
Reactive Radicals as Probes of a Polymer Structure
Material Science
Polymer chemists
used to study and evaluate macroscopic properties of polymers and polymer
articles (hardness, adhesion, elongation, stiffness, Tg, abrasion-resistance,
different thermal and mechanical properties, conductivity, etc.) Study of such
properties and evaluation of polymers not necessarily requires understanding of
their molecular structure. However, it is very desirable to understand polymer
structure and properties at a molecular level upon the study of permeability,
aging indoors and outdoors of polymers, the role of low MW impurities. Many
polymers or polymeric coatings prepared by free-radical photopolymerization
(UV-cure) have residual photo initiators (PI). Presence of PI and peculiarities
of a chemical structure of coatings affect their such important property as
weather ability.
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